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BlackOxy™

Activated sulfate-radical oxidation for complex landfill leachate and industrial wastewater

Advanced Leachate Treatment

Powerful two-component oxidation for difficult leachate contaminants

BlackOxy™ is a two-component treatment technology developed to support the oxidation of difficult organic contaminants in landfill leachate, wastewater, sludge and contaminated water.

BlackOxy™ combines a proprietary “Black” activator with an “Oxy” oxidizing component. When the components are introduced under controlled conditions, the activator is designed to accelerate oxidant decomposition and promote the formation of reactive sulfate radicals. These highly reactive species attack susceptible organic compounds, helping reduce colour, odour and difficult COD fractions while preparing the water for biological treatment, filtration or adsorption. Because landfill leachate composition changes with landfill age, waste composition, climate and operating conditions, every BlackOxy™ installation requires complete leachate analysis, laboratory treatability testing and site-specific process design.

Activate oxidation / Transform persistent pollution

BlackOxy Introduction

Advanced oxidation for challenging leachate and wastewater

BlackOxy™ can be incorporated into multistage treatment systems as an oxidation, pretreatment or remediation step before biological treatment, clarification, filtration, adsorption or membranes.

Landfill Leachate Treatment

Targets colour, odour and oxidisable organic contaminants in young, intermediate and mature landfill leachate.

In-Situ Landfill Treatment

Proposed for professionally controlled treatment of landfill waste, contaminated surfaces or collected leachate at its source.

Industrial Wastewater

Supports the oxidation of selected organic contaminants in complex industrial wastewater after compatibility testing.

High-COD Wastewater

Can transform selected refractory organic compounds and potentially improve the biodegradability of difficult wastewater.

Hydrogen Sulphide & Odour

Oxidises hydrogen sulphide and other susceptible odour-causing compounds under properly controlled reaction conditions.

Sludge, Soil & Contaminated Water

Proposed for selected remediation projects where direct application and oxidation have been validated through field trials.

Recommended Workflow

Recommended Treatment Sequence

Step-by-step process guide from leachate characterisation and treatability testing to biological polishing and verification.

BlackOxy™ Treatment Stages
Stage Process Description
Stage 1 — CharacterisationAnalyse COD, BOD, TOC, pH, alkalinity, ammonium, conductivity, chloride, metals, sulphide and site-specific contaminants.
Stage 2 — Treatability TestingDetermine oxidant demand, component ratio, reaction time and potential transformation products through laboratory testing.
Stage 3 — Controlled ActivationIntroduce the Black and Oxy components using an approved sequence, suitable mixing and compatible dosing equipment.
Stage 4 — Reaction & MonitoringMonitor pH, temperature, oxidation-reduction potential, residual oxidant, colour, COD and gas formation.
Stage 5 — Biological TreatmentWhere appropriate, use biological treatment for biodegradable oxidation products, ammonium conversion and nitrogen removal.
Stage 6 — Solids Separation & PolishingRemove precipitated or suspended solids and apply filtration, adsorption or membrane treatment where required.
Stage 7 — Final VerificationConfirm compliance through accredited analysis before discharge, reuse or environmental release.

Four complementary stages / For difficult leachate treatment

BLACK

Proprietary Oxidizer Activation (BLACK-ACTIVATION)

The Black component is described as a formulation containing activated carbon, metal-based activating components and alkaline chemistry that initiates the oxidation reaction.

OXY

Sulfate-Radical Generation (OXY-OXIDATION)

The Oxy component is activated to generate reactive sulfate-radical species capable of attacking susceptible organic contaminants.

BIO

Improved Downstream Biodegradation (BIOLOGICAL-SUPPORT)

Controlled partial oxidation may convert selected persistent organic compounds into smaller, more biodegradable intermediates for downstream biological treatment.

PURE

Filtration and Adsorption (FINAL-POLISHING)

Clarification, filtration or adsorption can remove suspended reaction products, precipitated contaminants and residual organic pollution following oxidation.

Science & Technology

BlackOxy™ is based on activated oxidation chemistry designed to produce sulfate radicals with higher selectivity and longer effective lifetimes than hydroxyl radicals under certain water conditions.

  • Activator and Oxidizer Combination – The Black component is added according to an approved sequence to activate the Oxy component (reaction speed depends on component ratio, temperature, pH and leachate composition).
  • Sulfate-Radical Formation – Activation of a suitable persulfate-based oxidizer produces the sulfate radical ($S_2O_8^{2-} \rightarrow 2SO_4^{\bullet-}$).
  • Organic-Contaminant Transformation – Sulfate radicals react with susceptible organic molecules through electron transfer, hydrogen abstraction and addition reactions, fragmenting complex contaminants.
  • Integrated Treatment – Oxidation alone may not remove every contaminant; downstream biological treatment, precipitation, clarification, filtration or adsorption is required to achieve final objectives.
BlackOxy Science and Technology
Operational Data

Technical Data & Safety Handling

Potential treatment benefits, technical information requirements, and safety guidance for BlackOxy™.

Potential Treatment Benefits
  • Reduction of selected COD and BOD fractions, colour and odour improvement
  • Oxidation of hydrogen sulphide and transformation of selected persistent organics
  • Potential improvement in downstream biodegradability and reduced load on downstream units
  • Flexible integration into existing treatment plants with a comparatively compact chemical footprint
Safety & Handling Guidelines
  • Consult current SDS for both Black and Oxy components; store components separately unless premixing is authorized.
  • Keep oxidizers away from heat, combustible material, reducing agents and incompatible chemicals.
  • Wear suitable gloves, chemical goggles, protective clothing and respiratory protection where required.
  • Use controlled mechanical dosing; monitor reaction temperature and pressure; never discharge untreated leachate based on appearance alone.

Explore the BlackOxy™
Poster Library

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BlackOxy Activated Leachate Treatment
Product Overview

BlackOxy™ Activated Leachate Treatment

An introduction to two-component oxidation for difficult landfill leachate.

Why Landfill Leachate Turns Black
Leachate Science

Why Landfill Leachate Turns Black

Understanding humic substances, decomposition, ammonium, sulphides and changing landfill conditions.

Black Activator + Oxy Oxidizer
Activation

Black Activator + Oxy Oxidizer

How controlled activation initiates sulfate-radical chemistry.

Advanced Sulfate-Radical Oxidation
Radical Chemistry

Advanced Sulfate-Radical Oxidation

Transforming selected refractory organic pollutants through powerful oxidation.

Reduce Difficult Organic Loading
COD Management

Reduce Difficult Organic Loading

Using oxidation before biological treatment, filtration or adsorption.

Target Hydrogen Sulphide
Odour Control

Target Hydrogen Sulphide

Oxidation support for sulphide and other odour-causing compounds.

Oxidise Separate and Polish
Process Integration

Oxidise, Separate and Polish

A multistage treatment approach for achieving site-specific discharge requirements.

Measure More Than Colour
Treatment Validation

Measure More Than Colour

Verifying COD, ammonium, metals, residual oxidant and toxicity before discharge.

Frequently
Asked Questions

Technical information about BlackOxy™ chemistry, landfill-leachate applications, system integration and safe operation.

Contact Support
What is BlackOxy™?
BlackOxy™ is a two-component activated oxidation treatment developed for difficult landfill leachate and selected industrial wastewaters.
What are the Black and Oxy components?
The brochure describes Black as the activator and Oxy as the oxidizing component. Their precise compositions, ratio and addition procedure must be obtained from the current TDS and SDS.
How does BlackOxy™ work?
The activator promotes oxidant decomposition and reactive sulfate-radical formation. These radicals react with susceptible organic and odorous compounds.
Which contaminants can it treat?
Potential targets include colour-causing organics, selected refractory COD compounds, volatile fatty acids, hydrogen sulphide and other oxidisable contaminants.
Does BlackOxy™ remove heavy metals?
Oxidation cannot destroy metals. It may change their oxidation state or support precipitation, but physical solids separation or adsorption is still required.
Can it remove ammonium?
Ammonium is not reliably eliminated by oxidation alone. Complete nitrogen removal normally requires nitrification followed by denitrification or another validated nitrogen-treatment process.
Is BlackOxy™ a biological treatment?
The oxidation reaction is chemical. It may support a subsequent biological process by transforming selected compounds, but the product should not be described as “100% biological.”
Can BlackOxy™ treat every type of leachate?
Leachate varies considerably. Treatability testing is necessary, and additional treatment stages may be required for salts, ammonia, PFAS, metals or other contaminants.
Can it replace reverse osmosis?
Not universally. Advanced oxidation and reverse osmosis address different contaminant groups. BlackOxy™ may reduce organic loading, while membranes may still be required for dissolved salts and other contaminants.
Does BlackOxy™ provide zero-liquid discharge?
Oxidation alone is not a zero-liquid-discharge process. ZLD normally requires water recovery combined with concentrate treatment, evaporation, crystallisation or another residual-management process.
How quickly can results be observed?
Visible colour or odour changes may occur relatively quickly, but treatment completion must be determined using analytical testing rather than appearance.
How is the correct dosage determined?
The correct dose and component ratio must be established through representative laboratory tests followed by a controlled pilot trial.

Get an advanced leachate treatment solution

It all starts with representative leachate analysis.

Send us your landfill leachate characteristics (COD, BOD, colour, heavy metals, flow rates) and treatment objectives. Our specialists will help evaluate BlackOxy™ for your facility.

Transforming Difficult Leachate Through Activated Radical Oxidation

Water treatment facility overview